Earth Science focuses on scientific questions: What effects does deforestation of the Amazon have on regional precipitation patterns? What greenhouse gases are emitted by hydro-power lakes in midlatitude mountain regions? How has replacing CFCs with FCFCs impacted stratospheric chemistry?
Sustainable Living focuses more on technology and personal choices. How can I tell what kind of wood to buy if I want to make sure it is sustainable? If I choose a Green Energy package in {country}, will it include biomass and hydro power even if those have some bad impacts? What kind of fridge might I buy if I want that it has no CFCs and no FCFCs?
Then there are questions related to policy. How does the London congestion charge affect urban air quality? How are emission targets enforced? Etc. This category is harder to place. Some fit here. Some on Sustainable Living. Some on Politics. Some on Economics. Perhaps some fit on two or three or four of those sites. I would judge it on a case-by-case basis. We can always migrate questions if the community thinks a question fits better elsewhere.